Application of iron-biochar composite in topsoil for simultaneous remediation of chromium-contaminated soil and groundwater: Immobilization mechanism and long-term stability

This study was aimed to prove the effectiveness and practicability of an integrated technology for simultaneous remediation of Cr-contaminated soil and groundwater. The remediation system was built by pumping Crcontaminated groundwater into top contaminated soil round after round, enabling the pre-applied iron-biochar composite (Fe-BC) in topsoil to stabilize Cr from both groundwater and soil. Immobilization ability and mechanism of Cr in soil were explored by toxicity characteristic leaching procedure test, scanning electron microscopy-elemental mapping, and X-ray photo spectroscopy. Hydrus-1D software was used to examine the long-term stability of immobilized Cr in soil. Results showed that Fe-BC-amended soil could remove about 71% Cr from contaminated groundwater. Meanwhile, Cr from both groundwater and soil was simultaneously immobilized in topsoil, leachability of Cr in which was reduced by over 81%. The immobilization of Cr in soil was attributed to the reduction of Cr(VI) into Cr(III) to form stable CrxFe(1-x)(OH)(3). After remediation, the average transport rate of Cr in the soil profile was only 0.420 cm y(-1) along with the local rainfall. Our study demonstrated that integrated technology could effectively remove Cr from groundwater and stabilize Cr in soil and the simultaneous remediation target for both soil and groundwater reached.