A photoluminescent metal-organic framework with threefold interpenetrated diamond topological net

被引：6

作者：

Yang, E. ^{[1
,2
]}

Ding, Qingrong ^{[1
,2
]}

Kang, Yao ^{[2
]}

Wang, Fei ^{[2
]}

机构：

[1] Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350007, Fujian, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1072卷

基金：

中国国家自然科学基金;

关键词：

MOFs; Zinc; Interpenetration; Topology; Photoluminescence; Crystal structure; COORDINATION POLYMERS; HYDROGEN STORAGE; COMPLEXES; NETWORKS;

D O I：

10.1016/j.molstruc.2014.05.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new 3D metal-organic framework, [Zn3(IN)61.DMF.H20 (I, H-IN = isonicotinic acid), has been solvothermally synthesized and structurally characterized by single crystal X-ray diffraction. Structural analysis shows that compound I possesses a three-dimensional framework with 4-connected threefold interpenetrated diamond (dia) topological network where the Zn(ID centers are all 4-coordinated. Moreover, the photoluminescent property of this compound is investigated in the solid state at room temperature. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：228 / 231

页数：4

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