Petrology of lower-middle Miocene Zoumi Flysch Fm. (Mesorif sub-domain, Rif belt, Morocco): first evidence of mixed mode provenance and geodynamic setting

The Zoumi Basin was generated in a collisional tectonic setting during the Lower-Middle Miocene. The syn-orogenic flysch deposits of the basin have been well investigated by petrographic and geochemical studies to characterize the composition, source to sink routing system, and tectonic setting of the Zoumi flysch. Forty-three sandstone samples and 45 mudstone samples have been gathered from six measured stratigraphic sections. These samples have been analyzed using XRD, XRF, inductively coupled plasma-mass spectrometry (ICP-MS) for mudrocks and petrographic investigation for sandstones. The Lower-Middle Miocene Zoumi flysch is defined as sublitharenites and quartzarenites according to mineralogical content. Detrital grains are commonly subangular to subrounded, poorly sorted, and rich in quartz grains. Point counting modal analysis leads to craton interior and recycled orogen provenance with significant first-cycle sediment supply and low sedimentary recycling. Several chemical ratios (Al2O3/TiO2, La/Th, Cr/Th, Th/Sc, Zr/Sc) as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomaly suggest a dominant felsic rock sources. However, V-Ni-La*4, V-Ni-Th*10, and Th/Sc vs. Cr/Th plots do not exclude a mafic supply source nature which is evidenced by numerous ophiolitic outcrops scattered throughout the Mesorifan Subdomain (Mesorifan Ophiolitic Suture Zone).