Effect of dielectric constants of ethanol-water and acetone-water mixtures on proton-ligand and metal-ligand stability constants of Cu(II)-o-aminobenzene sulphonic acid complexes

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作者
Sondawale, PJ [1 ]
Narwade, ML [1 ]
机构
[1] GOVT SCI COLL,GADCHIROLI,MAHARASHTRA,INDIA
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O6 [化学];
学科分类号
0703 ;
摘要
The interaction between Cu(II) and o-aminobenzene sulphonic acid has shown 1 : 1 and 1 : 2 complex formation. The complex formation has been investigated potentiometrically in different percentage of ethanol-water and acetone-water mixtures at (27 +/- 0.1 degrees C). The method of Bjerrum and Calvin, as modified by Irving and Rossotti, has been used in the the present work. It showed that proton-ligand and metal-ligand stability constants increased with increasing the percentage of ethanol-water and acetone-water mixtures.
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页码:224 / 233
页数:10
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