Rapid synthesis of aryl sulfides through metal-free C-S coupling of thioalcohols with diaryliodonium salts

被引：15

作者：

Wang, Dawei ^{[1
]}

Yu, Xin ^{[1
]}

Zhao, Keyan ^{[1
]}

Li, Liang ^{[1
]}

Ding, Yuqiang ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Food Colloids & Biotechnol, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China

来源：

TETRAHEDRON LETTERS | 2014年 / 55卷 / 42期

基金：

中国国家自然科学基金;

关键词：

C-S coupling; Metal free; Diaryliodonium; Rapid; Chemoselectivity; EFFICIENT SYNTHESIS; FACILE SYNTHESIS; ALPHA-ARYLATION; COPPER; PALLADIUM; LIGAND; THIOLS; CATALYST; IODIDES; HALIDES;

D O I：

10.1016/j.tetlet.2014.08.088

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient, general, and highly selective method for the synthesis of aryl sulfides has been developed through metal-free, direct C-S coupling from thioalcohols and diaryliodonium salts. Significantly, the reaction took only 10 min to complete and produced high yields at room temperature. Thus, this methodology proves its value as a versatile synthetic choice for a broad range of aryl sulfides, producing good to excellent yields. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：5739 / 5741

页数：3

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