Numerical and experimental investigation of the stability of radio-frequency (RF) discharges at atmospheric pressure

The stability and uniformity of a radio-frequency (RF) discharge is limited by a critical power density. Beyond this critical power density, instability occurs in the form of physical changes in the plasma (such as contraction due to arcing). The RF discharge used in this study is the non-equilibrium Atmospheric Pressure Plasma Jet (APPJ (R)) developed by Apjet, Inc. This discharge is known to operate uniformly in helium gas. However, for some proposed applications such as surface modification, there is a need to operate with reactive gases such as O-2. Our experimental studies show that addition of molecular gas to a discharge operating in helium increases its power density ( W cm(-2)), until it reaches the critical unstable arcing limit. Moreover, an increase in the frequency of operation ( from 13 to 27 MHz) allows the plasma to sustain higher molecular gas concentrations and power densities before instability occurs. Further, it is observed that this critical power density is dependent on the type of molecular gas added. These results provide a motivation for the development of a mathematical model that can provide insight into the causes of instability and potential methods of suppression. The two commonly studied modes of instability are (1) thermal instability (TI) and (2) alpha-gamma-arc mode transition. For the APPJ (R) discharge conditions, the development time scales of TI are much longer (similar to 1 ms) as compared with discharge oscillation period (similar to 100 ns). Hence, if the instability was indeed thermal, discharge frequency increase would have no consequence, contrary to experimental findings. A 1D fluid model based on the local field approximation is developed to study instability in APPJ (R) discharge. The analysis of modeling results confirmed our hypothesis that the instability development actually takes place via breakdown of sheath i.e. alpha-gamma-arc mode transition and not by TI.