When NHC Ligands Make a Difference in Gold Catalysis

被引：56

作者：

Gatineau, David ^{[1
]}

Goddard, Jean-Philippe ^{[1
]}

Mouries-Mansuy, Virginie ^{[1
]}

Fensterbank, Louis ^{[1
]}

机构：

[1] Univ Paris 06, Inst Parisien Chim Mol, CNRS, UMR 7201,Sorbonne Univ, F-75005 Paris, France

来源：

ISRAEL JOURNAL OF CHEMISTRY | 2013年 / 53卷 / 11-12期

关键词：

asymmetric catalysis; carbenes; catalysis; electrophilic activation; gold; N-HETEROCYCLIC CARBENES; ACYCLIC DIAMINOCARBENE COMPLEXES; ASYMMETRIC CATALYSIS; TANDEM REACTIONS; METAL-COMPLEXES; ALKYNES; CYCLOISOMERIZATION; CYCLOADDITIONS; HYDROAMINATION; 1,5-ENYNES;

D O I：

10.1002/ijch.201300059

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thanks to their unique electronic and steric properties, carbene ligands offer highly valuable features for catalysis, including homogenous gold catalysis. The use of carbene-gold complexes has improved existing reactions, either by modifying reactivity modes or by leading to highly asymmetric processes. These topics will be discussed on the basis of selected examples.

引用

页码：892 / 900

页数：9

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