NASICON type ordered mesoporous lithium-aluminum-titanium-phosphate as electrode materials for lithium-ion batteries

被引：21
|
作者：
Bhanja, Piyali [1 ]
Senthil, Chenrayan [2 ]
Patra, Astam Kumar [1 ]
Sasidharan, Manickam [2 ]
Bhaumik, Asim [1 ]
机构：
[1] Indian Assoc Cultivat Sci, Dept Mat Sci, Kolkata 700032, India
[2] SRM Univ, SRM Res Inst, Madras 603203, Tamil Nadu, India
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2017年 / 240卷
关键词：
Mesoporous materials; Lithium-aluminum-titanium-phosphate; Lithium ion battery; Anode material; Discharge-charge performances; TRANSITION-METAL PHOSPHATES; SENSITIZED SOLAR-CELLS; LONG CYCLE LIFE; MOLECULAR-SIEVES; AIR BATTERY; SOLID-ELECTROLYTE; CATHODE; CARBON; CONDUCTIVITY; CRYSTAL;
D O I：
10.1016/j.micromeso.2016.11.005
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
An ordered 2D-hexagonal mesoporous Lithium-Aluminum-Titanium-Phosphate (LATP-1) material has been synthesized by using cetyltrimethylammonium bromide (CTAB) as the structure directing agent (SDA) thorough hydrothermal route. After acid-ethanol extraction of the as-synthesized LATP-1 material, the extracted white solid product has been characterized thoroughly using small and wide angle powder X-ray diffraction (XRD), nitrogen adsorption/desorption analysis, X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FE-SEM), Ultra-high resolution transmission electron microscopy (UHR-TEM) and thermogravimetric analysis (TGA). Elemental analysis revealed 2.53% Li, 2.02% Al, 4.84% Ti, 28.16% P, 62.44% O in the mesoporous LATP-1 material. The template-extracted LATP-1 material has been employed as anode and cathode materials for lithium ion batteries: as an anode material, the LATP-1 electrode exhibits stable discharge-charge performances with delivered capacity of 121 mAh.g(-1) and 117 mAh.g(-1), respectively and a high coulombic efficiency. (C) 2016 Elsevier Inc. All rights reserved.
引用
收藏
页码：57 / 64
页数：8
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