Inhibition of Carbon Steel Corrosion in Neutral Calcareous Synthetic Water by Eruca sativa Extract

被引:10
|
作者
Ebdelly, Wahiba [1 ,2 ]
Ben Hassen, Samia [1 ]
Novoa, X. Ramon [3 ]
Ben Amor, Yasser [1 ]
机构
[1] Univ Carthage, Inst Super Sci & Technol Environm Borj Cedria, Lab Rech Sci & Technol Environm, Hammam Lif 2050, Tunisia
[2] Univ Tunis El Manar, Fac Sci Math Phys & Nat Tunis, Tunis 1002, Tunisia
[3] Univ Vigo, EEI, ENCOMAT Grp, Vigo, Spain
关键词
corrosion; plant extract; calcareous medium; carbon steel; magnetite; aragonite; MILD-STEEL; ADSORPTION PROPERTIES; CALCIUM-CARBONATE; ACIDIC MEDIUM; PERFORMANCE; DERIVATIVES; ROSMARINUS; ALUMINUM; LEAVES; DRUGS;
D O I
10.1134/S2070205119030110
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Here, by various electrochemical and analytical techniques, we have examined whether Eruca sativa aqueous extract can inhibit the corrosion of carbon steel in calcareous synthetic water. We detected differences in the morphology and phases of the films formed on the metallic surface under corrosion conditions. The electrochemical results suggest that, in the presence of E. sativa extract, the observed decrease in the corrosion current is associated with an increase in polarization resistance. EIS results reveal the presence of two time constants. The first one, at high frequency range (HF), is associated to the faradic process. The second one, at low frequency (LF), is related to the redox reaction occurring in the passive film. The highest inhibition efficiency, related to the large fraction of phenolic compounds present in the extract, can reach up to 95% with a dose of only 30 ppm.
引用
收藏
页码:591 / 602
页数:12
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