Permanganate oxidation of unsaturated alcohols in alkaline media

被引：5
|
作者：
Jáky, M [1 ]
Simon-Trompler, E [1 ]
机构：
[1] Hungarian Acad Sci, Chem Res Ctr, Inst Chem, H-1525 Budapest, Hungary
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 2002年 / 34卷 / 09期
关键词：
D O I：
10.1002/kin.10080
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A study was made on permanganate oxidation of olefinic and acetylenic alcohols in aqueous alkali media. Deprotonation constants of alcohols can be calculated from the kinetic data. The rate constant of alkoxide group oxidation exceeded that of the unsaturated bond. For oxidation of the alcoholic group a mechanism based on hydride ion transfer is proposed. (C) 2002 Wiley Periodicals, Inc.
引用
收藏
页码：561 / 567
页数：7
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