Mechanism of thermal isomerization of azobenzene in zeolite cavities

被引：16
|
作者：
Kuriyama, Y [1 ]
Oishi, S [1 ]
机构：
[1] Kitasato Univ, Sch Sci, Dept Chem, Sagamihara, Kanagawa 2288555, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 10期
关键词：
D O I：
10.1246/cl.1999.1045
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The life time of cis-azobenzene in zeolite supercage is twenty times longer than that in benzene at room temperature. The kinetic studies indicate that the thermal isomerization proceeds through inversion mechanism. Activation parameters show that the zeolite nanospace gives the same environment as that of gas phase.
引用
收藏
页码：1045 / 1046
页数：2
相关论文
共 50 条
  • [1] Photoisomerization of azobenzene in zeolite cavities
    Kojima, M
    Takagi, T
    Goshima, T
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 344 : 179 - 184
  • [2] Theoretical study of the isomerization mechanism of azobenzene and disubstituted azobenzene derivatives
    Crecca, Christina R.
    Roitberg, Adrian E.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (26): : 8188 - 8203
  • [3] Theoretical study of the isomerization mechanism of azobenzene and symmetrically disubstituted azobenzene Derivatives
    Crecca, Christina R.
    Roitberg, Adrian
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [4] ELUCIDATION OF THERMAL-ISOMERIZATION MECHANISM FOR AZOBENZENE IN A CHOLESTERIC LIQUID-CRYSTAL SOLVENT
    NERBONNE, JM
    WEISS, RG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (18) : 5953 - 5954
  • [5] Computational studies of the isomerization mechanism of azobenzene and its derivatives
    Sreedhara, Sandhya
    Heid, Cornelia
    Sharghi, Mohammadreza
    Goyal, Puja
    BIOPHYSICAL JOURNAL, 2024, 123 (03) : 544A - 544A
  • [6] CNDO/2 STUDY OF MECHANISM OF ISOMERIZATION AND CONFORMATION OF AZOBENZENE
    LJUNGGRE.S
    WETTERMA.G
    ACTA CHEMICA SCANDINAVICA, 1971, 25 (05): : 1599 - +
  • [7] STM study of isomerization mechanism for a single azobenzene derivative
    Kazuma, Emiko
    Han, Mina R.
    Oh, Junepyo
    Kim, Yousoo
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [8] A density functional theory study on the thermal and photochemical isomerization mechanism of 4,4′-azobenzene disulfonate
    Zhu, Yue
    Pu, Min
    Fang, De-Cai
    He, Jing
    Evans, David G.
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2010, 211 (2-3) : 89 - 98
  • [9] A MECHANISM FOR ISOMERIZATION OF HEXANES USING ZEOLITE CATALYSTS
    BOLTON, AP
    LANEWALA, MA
    JOURNAL OF CATALYSIS, 1970, 18 (01) : 1 - &
  • [10] Theoretical study on the isomerization mechanism of azobenzene derivatives on graphene substrate
    Zhang, Yue
    Zhao, Jianqiang
    Sun, Liqiang
    Yan, Xin
    Sun, Jiani
    STRUCTURAL CHEMISTRY, 2025, 36 (02) : 661 - 671
12345