Advances for Ruthenium Catalysts with Metal-Ligand Cooperation for Hydrogenation of Oxalates into Ethylene Glycol

被引：2

作者：

Fang, Xiaolong ^{[1
,2
]}

Duan, Ning ^{[1
]}

Zhang, Min ^{[1
]}

Li, Bin ^{[2
]}

机构：

[1] Anhui Jianzhu Univ, Key Lab Funct Mol Design & Interface Proc, Coll Mat & Chem Engn, Hefei 230601, Peoples R China

[2] Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Chem Pro Duct Alcohols Ethers, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 40卷 / 09期

基金：

中国国家自然科学基金;

关键词：

hydrogenation of oxalate; ethylene glycol; metal-ligand cooperation; ruthenium catalyst; CARBOXYLIC-ACID ESTERS; ASYMMETRIC HYDROGENATION; DIMETHYL OXALATE; SELECTIVE HYDROGENATION; STEREOSELECTIVE HYDROGENATION; COMPLEXES; KETONES; HYDRIDE; ALCOHOLS; MECHANISM;

D O I：

10.6023/cjoc202004017

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ethylene glycol (EG) is an important fundamental chemical material, which has been widely used in the production of industrial chemicals such as polyester. Catalytic hydrogenation of oxalate into EG is a key step in the "coal-to-EG" industrial route. Design of efficient catalysts for catalyzing the hydrogenation of oxalate esters is a research hotspot. The research progress of ruthenium catalysts with metal-ligand cooperation in the homogeneous catalytic hydrogenation of oxalate esters in the past decade is reviewed. Based on the relationship between the catalyst structures and properties, the catalytic hydrogenation mechanism is discussed, which provides a reference for the further design and development of new catalysts with excellent performance.

引用

页码：2692 / 2701

页数：10

共 65 条

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