Carboxymethyl cellulose lithium (CMC-Li) as a novel binder and its electrochemical performance in lithium-ion batteries

被引:45
|
作者
Qiu, Lei [1 ,2 ]
Shao, Ziqiang [1 ,2 ]
Wang, Daxiong [1 ,2 ]
Wang, Feijun [1 ,2 ]
Wang, Wenjun [1 ,2 ]
Wang, Jianquan [1 ,2 ]
机构
[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[2] Beijing Engn Technol Res Ctr Cellulose & Its Deri, Beijing, Peoples R China
关键词
Lithium battery; LiFePO4; Water-based binder; Cellulose derivative; Carboxymethyl cellulose lithium; NEGATIVE ELECTRODES; ANATASE TIO2; ANODES; NANOPARTICLES; POLYACRYLATE; CAPACITY; CATHODES; STORAGE; ENERGY;
D O I
10.1007/s10570-014-0274-7
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
The novel water-based binder CMC-Li is synthesized using cotton as a raw material. The mechanism of CMC-Li as a binder is reported. CMC-Li as a binder can increase the contents of Li+, improving the diffusion efficiency and specific capacity. The battery with CMC-Li as the binder retained 97.8 % of the initial reversible capacity after 200 cycles at 176 mAh g(-1), which is beyond the theoretical specific capacity of lithium iron phosphate (LiFePO4, LFP). The cyclic voltammetry and electrochemical impedance spectroscopy curves are weaker. The batteries obtain good electrochemical properties, are pollution free and have excellent stability.
引用
收藏
页码:2789 / 2796
页数:8
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