A phase transition in p-tert-butylcalix[8]arene solvated C60

被引：2
|
作者：
Gu, M [1 ]
Tang, TB
Wu, Y
Hu, C
Wu, XS
Xu, Z
Feng, D
机构：
[1] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Inst Solid State Phys, Nanjing 210093, Peoples R China
[3] Hong Kong Baptist Univ, Dept Phys, Hong Kong, Peoples R China
[4] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China
来源：
PHYSICS LETTERS A | 1999年 / 263卷 / 1-2期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0375-9601(99)00724-0
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
Differential scanning calorimetry has revealed the presence of an endothermal process at 150.0+/-0.5 K in the p-tert-butylcalix[8]arene(1:1)C-60, that is not associated with a structural change or a discontinuity. We attributed this event to a new orientational transition which is different from that in pristine C-60. At low-temperature, some change in the axis of reorientation of solvated C-60, molecules may be due to an interaction between C-60 and CH3 groups of the solvate, related with an unknown conformation of CH3 in the host. (C) 1999 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码：131 / 135
页数：5
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