Effect of Ru addition to CO/SiO2/HZSM-5 catalysts on Fischer-Tropsch synthesis of gasoline-range hydrocarbons

被引：44

作者：

Li, Yu-Ping ^{[1
]}

Wang, Tie-Jun ^{[1
]}

Wu, Chuang-Zhi ^{[1
]}

Qin, Xin-Xin ^{[1
]}

Tsubaki, Noritatsu ^{[2
]}

机构：

[1] Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China

[2] Toyama Univ, Dept Appl Chem, Sch Engn, Toyama 9308555, Japan

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 14期

关键词：

Fischer-Tropsch synthesis; Gasoline-range hydrocarbons; Ru adding; Ru-Co/SiO2/HZSM-5; catalyst; RU/SIO2; CATALYSTS; CO HYDROGENATION; ISO-PARAFFINS; SYNGAS; DEACTIVATION; PERFORMANCE; CONVERSION; RU/AL2O3; MN;

D O I：

10.1016/j.catcom.2009.06.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Microporous HZSM-5 zeolite and mesoporous SiO2 supported Ru-Co catalysts of various Ru adding amounts were prepared and evaluated for Fischer-Tropsch synthesis (FTS) of gasoline-range hydrocarbons (C-5-C-12). The tailor-made Ru-Co/SiO2/HZSM-5 catalysts possessed both micro- and mesopores, which accelerated hydrocracking/hydroisomerization of long-chain products and provided quick mass transfer channels respectively during FTS. In the same time. Ru increased Cor reduction degree by hydrogen spillover, thus CO conversion of 62.8% and gasoline-range hydrocarbon selectivity of 47%, including more than 14% isoparaffins, were achieved simultaneously when Ru content was optimized at 1 wt% in Ru-Co/SiO2/HZSM-5 catalyst. (c) 2009 Elsevier B.V. All rights reserved.

引用

页码：1868 / 1874

页数：7

共 50 条

[1] Gasoline-range hydrocarbon synthesis over cobalt-based Fischer-Tropsch catalysts supported on SiO2/HZSM-5
Li, Yuping
Wang, Tiejun
Wu, Chuangzhi
Lv, Yongxing
Tsubaki, Noritatsu
[J]. ENERGY & FUELS, 2008, 22 (03) : 1897 - 1901
[2] Fischer-Tropsch synthesis targeted to gasoline-range hydrocarbons
Zhu, Chunxiang
Paluch, Andrew
Bollas, George
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
[3] Improved Fischer-Tropsch synthesis for gasoline over Ru, Ni promoted Co/HZSM-5 catalysts
Wang, Shurong
Yin, Qianqian
Guo, Jinfeng
Ru, Bin
Zhu, Lingjun
[J]. FUEL, 2013, 108 : 597 - 603
[4] Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts
Liu, Shetian
Gujar, Amit C.
Thomas, Peter
Toghiani, Hossein
White, Mark G.
[J]. APPLIED CATALYSIS A-GENERAL, 2009, 357 (01) : 18 - 25
[5] The addition of HZSM-5 to the Fischer-Tropsch process for improved gasoline production
Botes, FG
Böhringer, W
[J]. APPLIED CATALYSIS A-GENERAL, 2004, 267 (1-2) : 217 - 225
[6] Ru modified Co/SiO2/HZSM-5 catalysts for jet fuel-range hydrocarbons synthesis
Li, Yu-Ping
Chen, Lun-Gang
Wang, Tie-Jun
Ma, Long-Long
Wu, Chuang-Zhi
Qiu, Song-Bai
[J]. Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2014, 42 (06): : 727 - 732
[7] Gasoline-range hydrocarbon synthesis over Co/SiO2/HZSM-5 catalyst with CO2-containing syngas
Li, Yu-ping
Wang, Tie-jun
Wu, Chuang-zhi
Li, Hai-bin
Qin, Xin-xin
Tsubaki, Noritatsu
[J]. FUEL PROCESSING TECHNOLOGY, 2010, 91 (04) : 388 - 393
[8] Development of highly selective Fischer-Tropsch catalysts for production of diesel- and gasoline-range hydrocarbons
Wang, Ye
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
[9] Hβ Modified Co/SiO2 Catalysts for Fischer-Tropsch Synthesis of Jet Fuel-range Hydrocarbons
Li Yu-Ping
Wang Tie-Jun
Ma Long-Long
Wu Chuang-Zhi
Ding Ming-Yue
[J]. JOURNAL OF INORGANIC MATERIALS, 2014, 29 (06) : 599 - 604
[10] Effect of Ru Promoter on Fischer-Tropsch Synthesis Performance of Co/SiO2 Catalyst
Gao Haiyan
Xiang Hongwei
Li Yongwang
[J]. CHINESE JOURNAL OF CATALYSIS, 2010, 31 (03) : 307 - 312

← 1 2 3 4 5 →