Assembly chemistry of a cadmium(II) complex with cyanometalate anions [Fe(CN)5NO]2-, [Pd(CN)4]2- and [Pt(CN)6]2-

被引：29

作者：

Zhang, H

Cai, JW ^{[1
]}

Feng, XL

Sang, HY

Liu, JZ

Li, XY

Ji, LN

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, State Key Lab Ultrafast Laser Spect, Guangzhou 510275, Peoples R China

[2] Zhongshan Univ, Instrumentat Anal & Res Ctr, Guangzhou 510275, Peoples R China

[3] Zhongshan Univ, Key Lab Gene Engn Minist Educ, Guangzhou 510275, Peoples R China

[4] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

POLYHEDRON | 2002年 / 21卷 / 07期

关键词：

cyanometalate; coordination polymers; crystal structures; cadmium(II) complexes;

D O I：

10.1016/S0277-5387(02)00846-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three complexes, namely [Cd(tren)][Fe(CN)(5)NO] (2), [Cd(tren)][Pd(CN)(4)] (3) and [Cd(tren)][Pt(CN)(6)] (4), were prepared via direct reactions of Na-2[Fe(CN)(5)NO], K-2[Pd(CN)(4)] and K-2[Pt(CN)(6)], respectively, with cadmium acetate and tris(2-aminoethyl)amine (tren) in aqueous solution. X-ray structural analysis shows that 2 features a shelf-like structure formed by stacking of the quasi-square building block. Compound 3 is a battlement-like polymer constructed from cyanometalate building blocks and compound 4 represents the first example of a cyano-bridged trinuclear hexacyanoplatinate(IV) complex. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：721 / 728

页数：8

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