Synthesis of 7-epi-Goniodiol by Proline-Catalyzed Diastereoselective Direct Aldol Reaction

被引：6

作者：

Veena, Bacchu ^{[1
]}

Sharma, Gangavaram V. M. ^{[1
]}

机构：

[1] Indian Inst Chem Technol, CSIR, Discovery Lab, Organ & Biomol Chem Div, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNLETT | 2014年 / 25卷 / 09期

关键词：

styryllactones; 7-epi-goniodiol; proline; aldol reaction; Baeyer-Villiger oxidation; GONIOTHALAMIN; LACTONES;

D O I：

10.1055/s-0033-1341107

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple organocatalytic approach was developed for the total synthesis of 7-epi-goniodiol. The strategy involves l-proline-catalyzed diastereoselective direct aldol reaction and Baeyer-Villiger oxidation as key steps for the construction of chiral lactone.

引用

页码：1283 / 1286

页数：4

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