Reactive Crystallization of Calcium Oxalate: Population Balance Modeling

被引：3

作者：

Rewatkar, K. ^{[1
]}

Shende, D. Z. ^{[1
]}

Wasewar, K. L. ^{[1
]}

机构：

[1] Visvesvaraya Natl Inst Technol, Dept Chem Engn, Adv Separat & Analyt Lab, Nagpur 440010, Maharashtra, India

来源：

CHEMICAL AND BIOCHEMICAL ENGINEERING QUARTERLY | 2018年 / 32卷 / 01期

关键词：

reactive crystallization; population balance model; method of moments; calcium oxalate; PRECIPITATION; KINETICS; SIZE; MONOHYDRATE; ACID;

D O I：

10.15255/CABEQ.2016.953

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Reactive crystallization of calcium oxalate has been studied to determine particle size distribution for calcium oxalate precipitation using population balance model with method of moments. The model is formulated and tested for single feed semi-batch reactive crystallization of calcium oxalate with reactants calcium chloride and sodium oxalate with literature data. The simulated results include local supersaturation distribution, number of particle distribution, mass of particle crystallized, particle size, nucleation and growth rate during the process. The model results are in good agreement with available experimental data from literature.

引用

页码：11 / 18

页数：8

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