Sinulariadiolide, a novel marine norditerpenoid from Okinawan soft coral of the genus, Sinularia

被引:24
|
作者
Iguchi, K [1 ]
Kajiyama, K [1 ]
Miyaoka, H [1 ]
Yamada, Y [1 ]
机构
[1] TOKYO UNIV PHARM & LIFE SCI,SCH PHARM,HACHIOJI,TOKYO 19203,JAPAN
来源
JOURNAL OF ORGANIC CHEMISTRY | 1996年 / 61卷 / 17期
关键词
D O I
10.1021/jo960044j
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new marine norditerpenoid, sinulariadiolide, was isolated from Okinawan soft coral of the genus, Sinularia. Its structure was determined by spectroscopic analysis and chemical reaction. This compound is structurally characterized. Toy a new carbon skeleton and two lactonic moieties, five-membered and nine-membered, the latter being conjugated to a 2-hydroxylated carbon-carbon double bond. A possible biogenesis of sinulariadiolide is briefly discussed.
引用
收藏
页码:5998 / 6000
页数:3
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