Preparation, Characterization, and Catalytic Activity of MoCo/USY Catalyst on Hydrodeoxygenation Reaction of Anisole

被引:0
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作者
Nugrahaningtyas, K. D. [1 ]
Suharbiansah, R. S. R. [2 ]
Rahmawati, F. [1 ]
机构
[1] Sebelas Maret Univ, Fac Math & Nat Sci, Chem Dept, Solid State & Catalysis, Jl Ir Sutami 36 A, Kentingan 57126, Surakarta, Indonesia
[2] Sebelas Maret Univ, Fac Math & Nat Sci, Chem Dept, Jl Ir Sutami 36 A, Kentingan 57126, Surakarta, Indonesia
关键词
D O I
10.1088/1757-899X/333/1/012060
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This research aims to prepare, characterize, and study the catalytic activity of Molybdenum (Mo) and Cobalt (Co) metal with supporting material Ultra Stable Y-Zeolite (USY), to produce catalysts with activity in hydrotreatment reaction and in order to eliminate impurities compounds that containing unwanted groups heteroatoms. The bimetallic catalysts MoCo/USY were prepared by wet impregnation method with weight variation of Co metal 0%, 2%, 4%, 6%, 8%, and Mo metal 8% (w/w), respectively. Activation method of the catalyst included calcination, oxidation, reduction and the crystallinity was characterized using X-ray diffraction (XRD), the acidity of the catalyst was analyzed using Fourier Transform Infrared Spectroscopy (FT-IR) and gravimetry method, minerals present in the catalyst was analyzed using X-Ray Fluorescence (XRF), and surface of the catalyst was analyzed using Surface Area Analyzer (SAA). Catalytic activity test (benzene yield product) of MoCo/USY on hydrodeoxigenation reaction of anisole aimed to determine the effect of Mo-Co/USY for catalytic activity in the reaction hydrodeoxigenation (HDO) anisole. Based on characterization and test of catalytic activity, it is known that catalytic of MoCo/USY 2% (catalyst B) shows best activities with acidity of 10.209 mmol/g, specific area of catalyst of 426.295 m(2)/g, pore average of 14.135 angstrom, total pore volume 0.318 cc/g, and total yield of HDO products 6.06%.
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页数:7
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