Chiral resolution of alcohols by extractive separation of acetals

被引：2
|
作者：
Mehraban, Keramatollah [1 ]
Gmeiner, Guenter [2 ]
Urban, Ernst [1 ]
Gaertner, Peter [2 ]
Eppacher, Simon [1 ]
Noe, Christian R. [1 ]
机构：
[1] Univ Vienna, Dept Med Chem, A-1090 Vienna, Austria
[2] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria
来源：
MONATSHEFTE FUR CHEMIE | 2014年 / 145卷 / 10期
关键词：
Acetal formation; Enantiomer selectivity; Extractive racemate resolution; Resolution of racemic alkylarylcarbinols; 2,3,3A,4,5,6,7,7A-OCTAHYDRO-7,8,8-TRIMETHYL-4,7-METHANOBENZOFURAN-2-YLPROTECTIV GROUP; TRIPHENYLPHOSPHINE HYDROBROMIDE; LACTOLS; RECOGNITION; ETHER;
D O I：
10.1007/s00706-013-1139-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new class of enantiomerically pure lactols is presented that react with rac-alkylarylcarbinols in high diastereoselectivity and can be used for the extractive racemate resolution of alkylarylcarbinols.
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页码：1631 / 1641
页数：11
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