Studies on reaction kinetics of o-Cresol novolac resin using phenol novolac acetate as curing agent by FTIR

被引：0
|
作者：
Luo, XW [1 ]
Li, SJ [1 ]
Ding, YD [1 ]
Ping, ZH [1 ]
机构：
[1] FUDAN UNIV,DEPT MACROMOL SCI,SHANGHAI 200433,PEOPLES R CHINA
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1997年 / 18卷 / 10期
关键词：
infrared spectroscopy; o-Cresol novolac resin; phenol novolac acetate; cure kinetic;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
FTIR in situ was used to study the isothermal reaction kinetics of o-cresol novolac resin using phenol novolac acetate as the curing agent in the presence of 2-methylimidazole. Some kinetic parameters of the curing reaction were. obtained, The results show that this curing process followed a first-order kinetics, The possible mechanism of cured reaction was discussed according to variation in absorption bands of C = O during the reaction.
引用
收藏
页码：1719 / 1723
页数：5
相关论文
共 14 条
  • [1] KINETICS OF EPOXY CURE .1. SYSTEM BISPHENOL-A DIGLYCIDYL ETHER/META PHENYLENE DIAMINE
    ACITELLI, MA
    PRIME, RB
    SACHER, E
    [J]. POLYMER, 1971, 12 (05) : 335 - &
  • [2] THERMAL-ANALYSIS OF THERMOSETTING RESINS
    ERA, VA
    MATTILA, A
    [J]. JOURNAL OF THERMAL ANALYSIS, 1976, 10 (03): : 461 - 469
  • [3] THE PHYSICAL BASIS OF MOISTURE TRANSPORT IN A CURED EPOXY-RESIN SYSTEM
    GUPTA, VB
    DRZAL, LT
    RICH, MJ
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (11) : 4467 - 4493
  • [4] CALORIMETRIC INVESTIGATION OF POLYMERIZATION REACTIONS .3. CURING REACTION OF EPOXIDES WITH AMINES
    HORIE, K
    HIURA, H
    SAWADA, M
    MITA, I
    KAMBE, H
    [J]. JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1970, 8 (06): : 1357 - &
  • [5] KAMAL MR, 1978, POLYM ENG SCI, V18, P728
  • [6] CURING REACTION OF O-CRESOL NOVOLAC EPOXY-RESIN ACCORDING TO HARDENER CHANGE
    KIM, WG
    LEE, JY
    PARK, KY
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (03) : 633 - 639
  • [7] EFFECT OF DIFFUSION CONTROL IN GLASS-TRANSITION REGION ON CRITICAL CONVERSION AT GEL POINT DURING CURING OF EPOXY-RESINS
    LUNAK, S
    VLADYKA, J
    DUSEK, K
    [J]. POLYMER, 1978, 19 (08) : 931 - 933
  • [8] CURE KINETICS OF EPOXY FORMULATIONS OF THE TYPE USED IN ADVANCED COMPOSITES
    MIJOVIC, J
    KIM, J
    SLABY, J
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1984, 29 (04) : 1449 - 1462
  • [9] MORONI A, 1986, J APPL POLYM SCI, V32, P761
  • [10] THERMAL-ANALYSIS OF EPOXY CURING USING POLYFUNCTIONAL ACTIVE ESTERS AS CURING AGENTS
    NAKAMURA, S
    SAEGUSA, Y
    YANAGISAWA, H
    TOUSE, M
    SHIRAI, T
    NISHIKUBO, T
    [J]. THERMOCHIMICA ACTA, 1991, 183 : 269 - 277
12