Catalytic enantioselective epoxidation of unfunctionalized olefins:: Utility of a Ti(Oi-Pr)4-salan-H2O2 system

被引：43
|
作者：
Matsumoto, Kazuhiro [1 ]
Sawada, Yuji [1 ]
Katsuki, Tsutomu [1 ]
机构：
[1] Kyushu Univ, Grad Sch, Fac Sci, Dept Chem,Higashi Ku, Fukuoka 8128581, Japan
来源：
SYNLETT | 2006年 / 20期
关键词：
asymmetric catalysis; epoxidations; titanium; hydrogen peroxide; salan ligand;
D O I：
10.1055/s-2006-956496
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Salan ligands bearing an ortho-substituted phenyl group at C3 and C3' were found to serve as an effective auxiliary of a Ti(Oi-Pr)(4)-salan-H2O2 system for enantioselective epoxidation. Simple olefins were converted into the corresponding epoxides in good to excellent enantioselectivity.
引用
收藏
页码：3545 / 3547
页数：3
相关论文
共 50 条
  • [1] Epoxidation of various functionalized olefins by a Ti-MWW/H2O2 catalytic system
    Li, Ningning
    Liu, Yueming
    Wu, Haihong
    Li, Xiaohong
    Xie, Wei
    Zhao, Zhonglin
    Wu, Peng
    He, Mingyuan
    CHINESE JOURNAL OF CATALYSIS, 2008, 29 (02) : 102 - 104
  • [2] Experimental and theoretical study on the reactivity of the R-CN/H2O2 system in the epoxidation of unfunctionalized olefins
    von Holleben, MLA
    Livotto, PR
    Schuch, CM
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2001, 12 (01) : 42 - 46
  • [3] Catalytic Asymmetric Bromination of Unfunctionalized Olefins with H2O as a Nucleophile
    Zhang, Xun
    Li, Jing
    Tian, Hua
    Shi, Yian
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (33) : 11658 - +
  • [4] CATALYTIC EPOXIDATION OF OLEFINS BY H2O2 METHYLRHENIUM TRIOXIDE
    ALAJLOUNI, AM
    ESPENSON, JH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 582 - INOR
  • [5] Epoxidation of Olefins by Ketone-H2O2 System
    Zheng, Yan-Song
    Xiao, Qin
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 2001, 22 (07):
  • [6] Epoxidation of olefins by ketone-H2O2 system
    Zheng, YS
    Xiao, Q
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2001, 22 (07): : 1155 - 1156
  • [7] Asymmetric epoxidation of olefins -: The first enantioselective epoxidation of unfunctionalised olefins catalysed by a chiral ruthenium complex with H2O2 as oxidant
    Stoop, RM
    Mezzetti, A
    GREEN CHEMISTRY, 1999, 1 (01) : 39 - 41
  • [8] Ti(Oi-Pr)4-Promoted Regio- and Stereoselective Aminolysis of 2,3-Epoxy Amides
    Righi, Giuliana
    Mantineo, Agnese
    Suber, Lorenza
    Mari, Alessandra
    SYNLETT, 2012, (13) : 1947 - 1949
  • [9] Ti-ferrierite and TiITQ-6:: synthesis and catalytic activity for the epoxidation of olefins with H2O2
    Corma, A
    Diaz, U
    Domine, ME
    Fornés, V
    CHEMICAL COMMUNICATIONS, 2000, (02) : 137 - 138
  • [10] Enantioselective Epoxidation of Olefins with H2O2 Catalyzed by Bioinspired Aminopyridine Manganese Complexes
    Shen, Duyi
    Qiu, Bin
    Xu, Daqian
    Miao, Chengxia
    Xia, Chungu
    Sun, Wei
    ORGANIC LETTERS, 2016, 18 (03) : 372 - 375
12345