Trapping Formaldehyde in the Homogeneous Catalytic Reduction of Carbon Dioxide

被引：84
|
作者：
Bontemps, Sebastien [1 ,2 ]
Sabo-Etienne, Sylviane [1 ,2 ]
机构：
[1] CNRS, LCC, F-31077 Toulouse, France
[2] Univ Toulouse, UPS, INPT, F-31077 Toulouse, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 39期
关键词：
acetals; borane; CO2; reduction; formaldehyde; ruthenium; N-HETEROCYCLIC CARBENE; NMR-SPECTROSCOPY; CO2; INSERTION; FORMIC-ACID; HYDROGENATION; METHANOL; CONVERSION; TRANSFORMATION; COMPLEX; TECHNOLOGIES;
D O I：
10.1002/anie.201304025
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Formaldehyde detectives: Evidence for the production of formaldehyde during a ruthenium-catalyzed CO2 reduction process, and for its involvement in the formation of the resulting C2 compound, is disclosed. Ultimately, formaldehyde can be recovered by methanol trapping. HBPin=pinacolborane. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10253 / 10255
页数：3
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