Metal-free regioselective C-C bond cleavage in 1,3,5-triazine derivatives of β-diketones

被引:7
|
作者
Kopylovich, Maximilian N. [1 ]
Mahmudov, Kamran T. [1 ,2 ]
Haukka, Matti [3 ]
Pombeiro, Armando J. L. [1 ]
机构
[1] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal
[2] Baku State Univ, Dept Chem, AZ-1148 Baku, Azerbaijan
[3] Univ Jyvaskyla, Dept Chem, FI-40014 Jyvaskyla, Finland
关键词
CARBON-CARBON BOND; NONHEME FE2+ CENTER; ACIREDUCTONE DIOXYGENASE; COPPER(II) COMPLEXES; CATALYTIC-ACTIVITY; ACTIVATION; CHEMISTRY; ARYLHYDRAZONES; REACTIVITY; RESONANCE;
D O I
10.1039/c3nj01292a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-free regioselective activation of a carbon-carbon bond in 1,3,5-triazine derivatives of beta-diketones is easily achieved, in the absence of a catalyst, with the assistance of intramolecular hydrogen bonding.
引用
收藏
页码:495 / 498
页数:4
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