Nonquiescent relaxation in entangled polymer liquids after step shear

被引:83
|
作者
Wang, Shi-Qing [1 ]
Ravindranath, Sham
Boukany, Pouyan
Olechnowicz, Michael
Quirk, Roderic P.
Halasa, Adel
Mays, Jimmy
机构
[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
[2] Univ Akron, Maurice Morton Inst Polymer Sci, Akron, OH 44325 USA
关键词
D O I
10.1103/PhysRevLett.97.187801
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Large step shear experiments revealed through particle tracking velocimetry that entangled polymeric liquids display either internal macroscopic movements upon shear cessation or rupturelike behavior during shear. Visible inhomogeneous motions were detected in five samples with the number of entanglements per chain ranging from 20 to 130 at amplitudes of step strain as low as 135%.
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页数:4
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