Synthesis and ESR spectra of [4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzosemiquinonato]thallium(I)

被引：12

作者：

Poddel'sky, AI ^{[1
]}

Abakumov, GA ^{[1
]}

Bubnov, MP ^{[1
]}

Cherkasov, VK ^{[1
]}

Abakumova, LG ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2004年 / 53卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

solvation; ESR spectroscopy; o-iminobenzoquinone; thallium;

D O I：

10.1023/B:RUCB.0000042272.46494.55

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[4,6-Di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzosemiquinonato]thallium(I) was synthesized and characterized by IR and ESR spectroscopy. The hyperfine coupling constants with Tl-203/205 nuclei were found to depend strongly on the nature (solvating ability) of solvents. At 298 K, the HFC constant a(Tl) changes from 3.09 mT in n-hexane up to 19.70 mT in tetramethylethylenediamine. The coordination number of solvation was found to be 1 for DMF-benzene and pyridine-hexane systems. The thermodynamic characteristics of solvation in the pyridine-hexane system were determined.

引用

页码：1189 / 1193

页数：5

共 50 条

[1] Synthesis and ESR spectra of [4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzosemiquinonato]thallium(i)
A. I. Poddel"sky
G. A. Abakumov
M. P. Bubnov
V. K. Cherkasov
L. G. Abakumova
Russian Chemical Bulletin, 2004, 53 : 1189 - 1193
[2] Polymerization of Vinyl Monomers in the Presence of 4,6-Di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone
Lizyakina, O. S.
Vaganova, L. B.
Chegerev, M. G.
Piskunov, A. V.
Grishin, D. F.
POLYMER SCIENCE SERIES B, 2019, 61 (02) : 132 - 147
[3] Polymerization of Vinyl Monomers in the Presence of 4,6-Di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone
O. S. Lizyakina
L. B. Vaganova
M. G. Chegerev
A. V. Piskunov
D. F. Grishin
Polymer Science, Series B, 2019, 61 : 132 - 147
[4] New germanium complexes containing ligands based on 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone in different redox states
Piskunov, Alexandr V.
Aivaz'yan, Igor A.
Poddel'sky, Andrey I.
Fukin, Georgii K.
Baranov, Evgenii V.
Cherkasov, Vladimir K.
Abakumov, Gleb A.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (09) : 1435 - 1444
[5] [4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Amidophenolato][4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Iminobenzosemiquinolato](2,2′-Bipyridyl)Indium(III)
Ershova, Irina V. V.
Cherkasov, Anton V. V.
Piskunov, Alexandr V. V.
MOLBANK, 2023, 2023 (02)
[6] Synthesis of linear block copolymers from methacrylic monomers using 4,6-di-tert-butyl-N-2,6-diisopropylphenyl)-o-iminobenzoquinone
O. S. Lizyakina
L. B. Vaganova
A. V. Piskunov
D. F. Grishin
Russian Chemical Bulletin, 2020, 69 : 1478 - 1485
[7] Synthesis of linear block copolymers from methacrylic monomers using 4,6-di-tert-butyl-N-2,6-diisopropylphenyl)-o-iminobenzoquinone
Lizyakina, O. S.
Vaganova, L. B.
Piskunov, A. V.
Grishin, D. F.
RUSSIAN CHEMICAL BULLETIN, 2020, 69 (08) : 1478 - 1485
[8] The Features of Interaction of Bis(4, 6-di-tert-butyl-N-(2, 6-diisopropylphenyl)-o-amidophenolato)tin(IV) with Bromine and Iodine
Ilyakina, Ekaterina V.
Poddel'sky, Andrey I.
Piskunov, Alexandr V.
Fukin, Georgii K.
Cherkasov, Vladimir K.
Abakumov, Gleb A.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (09): : 1323 - 1327
[9] Oxidative addition of 3,6-di-tert-butyl-o-benzoquinone and 4,6-di-tert-butyl-N-(2,6-di-iso-propylphenyl)-o-iminobenzoquinone to SnCl2
Lado, AV
Poddel'sky, AI
Piskunov, AV
Fukin, GK
Baranov, EV
Ikorskii, VN
Cherkasov, VK
Abakumov, GA
INORGANICA CHIMICA ACTA, 2005, 358 (15) : 4443 - 4450
[10] Radical polymerization of methyl methacrylate in the presense of bis[4,6-di-tert-butyl-N-(2,6-dimethylphenyl)-o-iminobenzosemiquinono]cobalt(II)
Kolyakina, E. V.
Poddel'skii, A. I.
Grishin, D. F.
RUSSIAN CHEMICAL BULLETIN, 2014, 63 (04) : 987 - 996

← 1 2 3 4 5 →