The 23Δg State of 7Li2

被引:18
|
作者
Dai, XC
Clevenger, JO
Liu, YM
Song, M
Shang, JY
Chen, DY
Field, RW
Li, L [1 ]
机构
[1] Tsing Hua Univ, Dept Phys, Beijing 100084, Peoples R China
[2] Tsing Hua Univ, Ctr Atom & Mol Sci, Beijing 100084, Peoples R China
[3] MIT, Dept Chem, Cambridge, MA 02139 USA
基金
中国国家自然科学基金;
关键词
Li-7(2); PFOODR; Rydberg state; triplet state; 2(3)Delta(g);
D O I
10.1006/jmsp.1999.8033
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Using pulsed perturbation-facilitated optical-optical double resonance (PFOODR) spectroscopy, the 2(3)Delta(g) state of Li-7(2) (electronic configuration (sigma(8)2s) (4d delta(8)), effective principal quantum number n* = 4.101) has been observed and assigned. Molecular constants and a RKR potential energy curve were obtained, The major molecular constants are T-e(cm(-1)) omega(e)(cm(-1)) B-e(cm(-1)) / 2(3)Delta(g) 35 014.1(33) 265.68(88) 0.5115(18 (C) 2000 Academic Press.
引用
收藏
页码:120 / 122
页数:3
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