Intermolecular Casimir-Polder forces in water and near surfaces

被引：9

作者：

Thiyam, Priyadarshini ^{[1
]}

Persson, Clas ^{[1
,2
,3
]}

Sernelius, Bo E. ^{[4
]}

Parsons, Drew F. ^{[5
]}

Malthe-Sorenssen, Anders ^{[2
]}

Bostrom, Mathias ^{[1
,3
,6
]}

机构：

[1] Royal Inst Technol, Dept Mat Sci & Engn, SE-10044 Stockholm, Sweden

[2] Univ Oslo, Dept Phys, NO-0316 Oslo, Norway

[3] Univ Oslo, Ctr Mat Sci & Nanotechnol, NO-0316 Oslo, Norway

[4] Linkoping Univ, Dept Phys Chem & Biol, Div Theory & Modeling, SE-58183 Linkoping, Sweden

[5] Australian Natl Univ, Dept Appl Math, Canberra, ACT, Australia

[6] Norwegian Univ Sci & Technol, Dept Energy & Proc Engn, NO-7491 Trondheim, Norway

来源：

PHYSICAL REVIEW E | 2014年 / 90卷 / 03期

基金：

瑞典研究理事会;

关键词：

DISPERSION INTERACTIONS; ENERGY;

D O I：

10.1103/PhysRevE.90.032122

中图分类号：

O35 [流体力学]; O53 [等离子体物理学];

学科分类号：

070204 ; 080103 ; 080704 ;

摘要：

The Casimir-Polder force is an important long-range interaction involved in adsorption and desorption of molecules in fluids. We explore Casimir-Polder interactions between methane molecules in water, and between a molecule in water near SiO2 and hexane surfaces. Inclusion of the finite molecular size in the expression for the Casimir-Polder energy leads to estimates of the dispersion contribution to the binding energies between molecules and between one molecule and a planar surface.

引用

页数：6

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