Reaction pathway studies of C6 hydrocarbons on palladium model catalysts:: effects of hydrogen/hydrocarbon ratio, molecular structure, surface structure and temperature

被引：21
|
作者：
Ramos, ALD
Kim, SH
Chen, PL
Song, JH
Somorjai, GA [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
[3] Univ Fed Rio de Janeiro, EQ, COPPE, NUCAT, BR-21941 Rio De Janeiro, Brazil
来源：
CATALYSIS LETTERS | 2000年 / 66卷 / 1-2期
关键词：
hexane; palladium model catalysts; Pd(111); hydrogenolysis; hydrocracking; hydrogen; hydrocarbons;
D O I：
10.1023/A:1019091305212
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Reaction pathways of C-6 hydrocarbons, such as hydrogenolysis, dehydrogenation, aromatization and dehydrocyclization, have been studied on small surface area palladium model catalysts, including Pd(111) single crystal and polycrystalline palladium foil. These reactions were performed in a batch reactor, at atmospheric pressure and at two different temperatures (573 and 673 K).
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页码：5 / 11
页数：7
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