Lead halide perovskites for photocatalytic organic synthesis

被引:293
|
作者
Zhu, Xiaolin [1 ]
Lin, Yixiong [1 ]
San Martin, Jovan [1 ]
Sun, Yue [1 ]
Zhu, Dian [1 ]
Yan, Yong [1 ]
机构
[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA
基金
美国国家科学基金会;
关键词
LIGHT PHOTOREDOX CATALYSIS; ANION-EXCHANGE; HIGHLY LUMINESCENT; OPTICAL-PROPERTIES; NANOCRYSTALS; ELECTRON; LIGAND; BR; CL; ALKYLATION;
D O I
10.1038/s41467-019-10634-x
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Nature is capable of storing solar energy in chemical bonds via photosynthesis through a series of C-C, C-O and C-N bond-forming reactions starting from CO2 and light. Direct capture of solar energy for organic synthesis is a promising approach. Lead (Pb)-halide perovskite solar cells reach 24.2% power conversion efficiency, rendering perovskite a unique type material for solar energy capture. We argue that photophysical properties of perovskites already proved for photovoltaics, also should be of interest in photoredox organic synthesis. Because the key aspects of these two applications are both relying on charge separation and transfer. Here we demonstrated that perovskites nanocrystals are exceptional candidates as photocatalysts for fundamental organic reactions, for example C-C, C-N and C-O bond-formations. Stability of CsPbBr3 in organic solvents and ease-of-tuning their bandedges garner perovskite a wider scope of organic substrate activations. Our low-cost, easy-to-process, highly-efficient, air-tolerant and bandedge-tunable perovskites may bring new breakthrough in organic chemistry.
引用
收藏
页数:10
相关论文
共 50 条
  • [1] Lead halide perovskites for photocatalytic organic synthesis
    Zhu, Xiaolin
    Lin, Yixiong
    Sun, Yue
    Zhu, Dian
    Yan, Yong
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [2] Lead halide perovskites for photocatalytic organic synthesis
    Xiaolin Zhu
    Yixiong Lin
    Jovan San Martin
    Yue Sun
    Dian Zhu
    Yong Yan
    [J]. Nature Communications, 10
  • [3] Lead-halide perovskites for photocatalytic organic synthesis
    Yan, Yong
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [4] Crystal structure engineering of metal halide perovskites for photocatalytic organic synthesis
    Wang, Chunhua
    Ding, Yang
    Liu, Biao
    Weng, Bo
    Hofkens, Johan
    Roeffaers, Maarten B. J.
    [J]. CHEMICAL COMMUNICATIONS, 2023, 59 (21) : 3122 - 3125
  • [5] Lead-Halide Perovskites for Photocatalytic α-Alkylation of Aldehydes
    Zhu, Xiaolin
    Lin, Yixiong
    Sun, Yue
    Beard, Matthew C.
    Yan, Yong
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (02) : 733 - 738
  • [6] Lead halide perovskites for effective photocatalytic selective oxysulfenylation of alkenes
    Zhang, Honglei
    Zhong, Yangbo
    Yang, Liu
    Fan, Qiangwen
    Le, Zhanggao
    Xie, Zongbo
    Zhu, Haibo
    [J]. MOLECULAR CATALYSIS, 2024, 564
  • [7] Giant photostriction in organic–inorganic lead halide perovskites
    Yang Zhou
    Lu You
    Shiwei Wang
    Zhiliang Ku
    Hongjin Fan
    Daniel Schmidt
    Andrivo Rusydi
    Lei Chang
    Le Wang
    Peng Ren
    Liufang Chen
    Guoliang Yuan
    Lang Chen
    Junling Wang
    [J]. Nature Communications, 7
  • [8] Methodologies for structural investigations of organic lead halide perovskites
    Kim, Tae Woong
    Park, Nam-Gyu
    [J]. MATERIALS TODAY, 2020, 38 : 67 - 83
  • [9] Laser Direct Write Synthesis of Lead Halide Perovskites
    Chou, Stanley S.
    Swartzentruber, Brian S.
    Janish, Matthew T.
    Meyer, Kristin C.
    Biedermann, Laura B.
    Okur, Serdal
    Burckel, D. Bruce
    Carter, C. Barry
    Kaehr, Bryan
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2016, 7 (19): : 3736 - 3741
  • [10] Giant photostriction in organic-inorganic lead halide perovskites
    Zhou, Yang
    You, Lu
    Wang, Shiwei
    Ku, Zhiliang
    Fan, Hongjin
    Schmidt, Daniel
    Rusydi, Andrivo
    Chang, Lei
    Wang, Le
    Ren, Peng
    Chen, Liufang
    Yuan, Guoliang
    Chen, Lang
    Wang, Junling
    [J]. NATURE COMMUNICATIONS, 2016, 7