Recent applications of the hetero Diels-Alder reaction in the total synthesis of natural products

被引:105
|
作者
Heravi, Majid M. [1 ]
Ahmadi, Tahereh [1 ]
Ghavidel, Mahdieh [1 ]
Heidari, Bahareh [1 ]
Hamidi, Hoda [1 ]
机构
[1] Alzahra Univ, Dept Chem, Tehran, Iran
基金
美国国家科学基金会;
关键词
ENANTIOSELECTIVE TOTAL-SYNTHESIS; FORMAL TOTAL-SYNTHESIS; POLYHYDROXYLATED NORTROPANE DERIVATIVES; STEREOSELECTIVE TOTAL-SYNTHESIS; ASYMMETRIC TOTAL SYNTHESES; STEREOCONTROLLED TOTAL-SYNTHESIS; RUTHENIUM-CATALYZED HYDRATION; OCCURRING TERPENE DERIVATIVES; SPONGE AGELAS-DENDROMORPHA; CONCISE TOTAL-SYNTHESIS;
D O I
10.1039/c5ra17488k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthetic utility and potential power of the Diels-Alder (D-A) reaction in organic chemistry is evident. These significances have been extended to the synthesis of a plethora and wide variety of heterocyclic compounds via [4 + 2] cycloaddition reactions, the so called hetero Diels-Alder (HDA) reaction. In this work we try to focus on the scope and preparative synthetic applications of the HDA reaction as a key step in the total synthesis of natural products.
引用
收藏
页码:101999 / 102075
页数:77
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