trans-Diaquabis(2-pyridylethanol-N,O)nickel(II) disaccharinate

被引：8
|
作者：
Hamamci, S
Yilmaz, VT [1 ]
Thöne, C
机构：
[1] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Turkey
[2] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词：
D O I：
10.1107/S160053680202007X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [ Ni( pyet)(2)( H2O)(2)]( sac)(2) ( sac(-) is the saccharinate anion, C7H4NO3S-, and pyet is 2- pyridylethanol, C7H9NO), is built of discrete sac(-) and [ Ni( H2O)(2)( pyet)(2)](2+) ions. The Co2+ ion sits on a centre of symmetry and exhibits a distorted octahedral geometry, formed by two bidentate pyet and two water molecules. The crystal structure is stabilized by hydrogen- bonding and weak aromatic pi - pi- stacking interactions between the planar sac(-) ions, forming a three-dimensional network.
引用
收藏
页码：M700 / M701
页数：2
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