Chemical changes in heavy metals in the leachates from Technosols

A 2 month long column study was conducted to evaluate the mobility of heavy metals eluting from Technosols constituted from sewage sludges (aerobic or anaerobic) (as controls) or a mixture of different types of sewage sludges with green foundry sand (FS) or/and Linz-Donowitz slag (LD). The organic and inorganic wastes were mixed at a ratio of 56:44 (w/w). The mixtures and the controls were moistened to field capacity before adding them to the polypropylene columns (4.5 cm wide and 14 cm long). During the 8-week experimental period, the columns were watered, twice a week, with 100 mL of deionised water. The concentrations of heavy metals (Cu, Zn, Ni, Pb, Cd, and Cr) in the leachates were determined periodically. The concentrations of all the heavy metals were generally higher in the leachates from the Technosols containing anaerobic sewage sludge as a component. The concentration of Cu was strongly dependent on pH and was significantly higher (P < 0.05) in the most alkaline leachates (pH > 10) than in the other leachates. More Zn was mobilized in the most acidic leachates (pH < 6) than in other leachates. The concentration of Ni in 80% of the leachates exceeded the EU drinking water limit for Ni (0.02 mg L-1). The concentrations of Pb were lower in the Technosols containing FS. The concentrations of Cd in the leachates from Technosols containing the conditioners were relatively high, while concentrations of Cr were higher in the controls. As far as the potential toxicity of heavy metals is concerned, the combination of aerobic sludge, inorganic conditioners able to buffer the pH to around neutrality, and reactive aluminosilicates, can be regarded as suitable choice for formulating Technosols from wastes. (C) 2009 Elsevier Ltd. All rights reserved.