Synthesis of C-3 branched allyl and pentadienyl glucosamines via radical coupling of sugar-thionocarbonates

被引：4
|
作者：
Wan, Q [1 ]
Lubineau, A [1 ]
Scherrmann, MC [1 ]
机构：
[1] Univ Paris 11, ICMMO, UMR 8614, Lab Chim Organ Multifonct, F-91405 Orsay, France
来源：
JOURNAL OF CARBOHYDRATE CHEMISTRY | 2004年 / 23卷 / 2-3期
关键词：
C-branched alkenyl sugars; radical reaction; pentadienyltributyltin; allyltributyltin; thionocarbonates;
D O I：
10.1081/CAR-120030469
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The intermolecular AIBN-promoted free radical reaction of glucosamine thionocarbonates as radical donors, and allyl or pentadienyl-tributyltin reagents gave the expected C-3 branched sugar derivatives in good yield and with total equatorial selectivity.
引用
收藏
页码：83 / 93
页数：11
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