Bis[bis(triphenylphosphoranylidene)-ammonium] pentachlorofluoroosmate(IV) hydrate, [(C6H5)(3)P=N=P(C6H5)(3)](2)-[OsFCl5].H2O

被引：4

作者：

Bruhn, C

Preetz, W

机构：

[1] Inst. für Anorganische Chemie, Universität Kiel, D-24098 Kiel

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S010827019601061X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title compound, (C36H30NP2)(2-) [OsCl5F].H2O, has been determined by single-crystal X-ray diffraction at 208 K. The octahedral [OsCl5F](2-) complex anions are completely ordered in an A(2)B-type lattice. The monoclinic unit cell contains four formula units, each with a solvent water molecule linked to the F atom by a hydrogen bond [O ... F 2.737 (8) Angstrom]. The Os-F bond [1.960(4) Angstrom] is weakened by trans influence and, correspondingly, the Os-Cl1 bond [2.307 (2) Angstrom] trans to Os-F is strengthened compared with the average Os-Cl bond length along the Cl-Os-Cl axes of 2.339 Angstrom.

引用

页码：63 / 66

页数：4

共 50 条

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