Determination of phenols by solid-phase microextraction

被引：115
|
作者：
Bartak, P
Cap, L
机构：
[1] Department of Analytical Chemistry, Palacký University, 77 146 Olomouc
来源：
JOURNAL OF CHROMATOGRAPHY A | 1997年 / 767卷 / 1-2期
关键词：
extraction methods; water analysis; phenols; nitrophenols; chlorophenols;
D O I：
10.1016/S0021-9673(96)01090-4
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Solid-phase microextraction was investigated for the determination of phenols. Analytes were extracted by a thin layer of suitable sorbent coated on a fine fused-silica fiber. The fiber was then transferred into the injection port of a gas chromatograph, analytes were thermally desorbed and analyzed by gas chromatography. The best results were obtained with a polyacrylate coating by indirectly sampling in the head space above the liquid sample. The extraction period was 60 min, the desorption time was 8 min at 250 degrees C. Acidification by hydrochloric acid (pH similar to 1) and salting out (saturation by sodium chloride) were necessary for the best recovery.
引用
收藏
页码：171 / 175
页数：5
相关论文
共 50 条
  • [1] OPTIMIZATION OF SOLID-PHASE MICROEXTRACTION CONDITIONS FOR DETERMINATION OF PHENOLS
    BUCHHOLZ, KD
    PAWLISZYN, J
    [J]. ANALYTICAL CHEMISTRY, 1994, 66 (01) : 160 - 167
  • [2] Determination of phenols in soils by in situ acetylation headspace solid-phase microextraction
    Llompart, Maria
    Blanco, Belen
    Cela, Rafael
    [J]. Journal of Microcolumn Separation, 2000, 12 (01): : 25 - 32
  • [3] Headspace solid-phase microextraction for direct determination of volatile phenols in cider
    Pizarro, Consuelo
    Perez-del-Notario, Nuria
    Maria Gonzalez-Saiz, Jose
    [J]. JOURNAL OF SEPARATION SCIENCE, 2009, 32 (21) : 3746 - 3754
  • [4] Determination of phenols in soils by in situ acetylation headspace solid-phase microextraction
    Llompart, M
    Blanco, B
    Cela, R
    [J]. JOURNAL OF MICROCOLUMN SEPARATIONS, 2000, 12 (01) : 25 - 32
  • [5] DETERMINATION OF PHENOLS BY SOLID-PHASE MICROEXTRACTION AND GAS-CHROMATOGRAPHIC ANALYSIS
    BUCHHOLZ, KD
    PAWLISZYN, J
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1993, 27 (13) : 2844 - 2848
  • [6] Determination of haloethers in water by solid-phase microextraction
    Huang, SD
    Ting, CY
    Lin, CS
    [J]. JOURNAL OF CHROMATOGRAPHY A, 1997, 769 (02) : 239 - 246
  • [7] Optimisation of headspace solid-phase microextraction for the analysis of volatile phenols in wine
    Meijías, RC
    Marín, RN
    Moreno, MDG
    Barroso, CG
    [J]. JOURNAL OF CHROMATOGRAPHY A, 2003, 995 (1-2) : 11 - 20
  • [8] Oxidized multiwalled carbon nanotubes as a novel solid-phase microextraction fiber for determination of phenols in aqueous samples
    Liu, Xiaoyan
    Ji, Yongsheng
    Zhang, Yonghui
    Zhang, Haixia
    Liu, Mancang
    [J]. JOURNAL OF CHROMATOGRAPHY A, 2007, 1165 (1-2) : 10 - 17
  • [9] Optimisation of a simple and reliable method based on headspace solid-phase microextraction for the determination of volatile phenols in beer
    Pizarro, C.
    Perez-del-Notario, N.
    Gonzalez-Saiz, J. M.
    [J]. JOURNAL OF CHROMATOGRAPHY A, 2010, 1217 (39) : 6013 - 6021
  • [10] Solid-phase microextraction
    Hinshaw, JV
    [J]. LC GC NORTH AMERICA, 2003, 21 (11) : 1056 - +
12345