A new, high electrochemical activity and chromium tolerant cathode for solid oxide fuel cells

The commercialization of solid oxide fuel cell (SOFC) technologies requires the development of cathode materials not only with high electrochemical activity and stability but also with excellent tolerance and resistance towards contaminants such as chromium. Here, a new electrode, Sm0.5(1-x)Sr0.5(1-x)BaxCo1-0.3xFe0.2xNb0.1xO3-delta (SSBCFN with x = 0.4, 0.5, 0.6) is developed based on the combined composition of Sm0.5Sr0.5CoO3-delta (SSC) and Ba(Co0.7Fe0.2Nb0.1)O3-delta (BCFN). SSBCFN with x = 0.5 (SSBCFN5) shows a high electronic conductivity of 128-221 S cm(-1) in the temperature range of 500-900 degrees C, an essential requirement of SOFCs electrode materials and low electrode polarization resistance of 0.53 Omega cm(2) at 600 degrees C, significantly lower than 1.79 Omega cm(2) for the reaction on SSC and 0.64 Omega cm(2) on BCFN. SSBCFN5 shows cubic perovsldte structure with a high oxygen non-stoichiometry, delta = 0.514 +/- 0.027, based on chemical titration method. Compared to SSC and BCFN electrodes, SSBCFN5 shows better electrochemical activity for the oxygen reduction reaction and most importantly, it exhibits excellent stability and resistance toward chromium deposition and poisoning under SOFC operation conditions from 700 to 900 degrees C. The results indicate that SSBCFN5 is a promising potential cathode of SOFCs with high activity, stability and high tolerance towards contamination by Cr. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.