Stationary and non-stationary processes in non-classical radical polymerization with size dependent termination

被引：4
|
作者：
Bamford, CH
机构：
来源：
MACROMOLECULAR SYMPOSIA | 1996年 / 111卷
关键词：
D O I：
10.1002/masy.19961110117
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Kinetic analysis of non-classical radical polymerization is discussed in terms of the Group-Termination Procedure on the basis of the geometric mean approximation. Expressions for important kinetic functions of stationary reactions, with or without chain-transfer, are listed and compared with their classical counterparts. In the treatment of non-stationary reactions (with or without transfer) special attention is paid to the calculation of pre- and after-effects and their applications in the evaluation of absolute rate coefficients.
引用
收藏
页码：171 / 181
页数：11
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