Silver complexes of a novel tripodal N-heterocyclic carbene ligand:: Evidence for significant metal-carbene π-interaction

被引：173

作者：

Hu, XL ^{[1
]}

Tang, YJ ^{[1
]}

Gantzel, P ^{[1
]}

Meyer, K ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 04期

关键词：

D O I：

10.1021/om020935j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel N-heterocyclic tridentate polycarbene ligand has been synthesized and stabilized as its corresponding silver complex. An electronic structure investigation reveals significant pi-bonding interactions within the Ag-carbene unit of the [(TIMEMe)(2)Ag-3](3+) cation.

引用

页码：612 / 614

页数：3

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