Hydrothermal synthesis and structure of [(PbCl2)(μ-Pyz)1/2]n (Pyz = pyrazine)

被引：0

作者：

Liao Qiu-Xia ^{[1
]}

Zhang Jian ^{[1
]}

Qin Ye-Yan ^{[1
]}

Yao Yuan-Gen ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 07期

关键词：

crystal structure; lead chloride; pyrazine;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 2-D lead-containing hybrid compound, [(PbCl2)(mu-Pyz)(1/2)](n) (Pyz = pyrazine) 1, has been synthesized by the hydrothermal assembly of pyrazine with lead chloride. Elemental analysis and X-ray crystal structure analyses were carried out for the structural determination and characterization of the title compound. Compound 1 crystallizes in orthorhombic, space group 15am, with a = 19.5558(18), b = 7.1939(6), c = 7.5449(6) angstrom, V = 1061.44(16) angstrom(3), C2H2Cl2NPb, M-r = 318.14, Z = 8, D-c = 3.982 g/cm(3), mu = 32.63 mm(-1), F(000) = 1096.0, R = 0.0368 and wR = 0.0901 for 623 observed reflections (I > 2 sigma(I)).

引用

页码：789 / 792

页数：4

共 50 条

[1] Hydrothermal Synthesis and Structure of [（PbCl2）(μ-Pyz)1/2]n （Pyz = Pyrazine）
LIAO Qiu-Xia ZHANG Jian QIN Ye-Yan YAO Yuan-Gen (State Key Laboratory of Structural Chemistry
Chinese Journal of Structural Chemistry, 2006, (07) : 789 - 792
[2] HydrothermalSynthesisandStructureof[（PbCl2）(μ-Pyz)1/2]_n（Pyz=Pyrazine）
LIAO QiuXia ZHANG Jian QIN YeYan YAO YuanGen State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China
结构化学, 2006, (07) : 789 - 792
[3] Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz = pyrazine)
Shi, YJ
Chen, XT
Cai, CX
Zhang, Y
Xue, ZL
You, XZ
Peng, SM
Lee, GH
INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (08) : 621 - 624
[4] Crystal structure and metamagnetic property of a 2-D layered complex, [FeII(N3)2(pyz)]n (pyz = pyrazine)
Hao, X
Wei, YG
Zhang, SW
CHEMICAL COMMUNICATIONS, 2000, (22) : 2271 - 2272
[5] The structural characterization of the novel ribbon sheet, [Cu2Cl2(pyz)](n) (pyz=pyrazine)
Kawata, S
Kitagawa, S
Kumagai, H
Iwabuchi, S
Katada, M
INORGANICA CHIMICA ACTA, 1998, 267 (01) : 143 - 145
[6] Magnetic ordering and spin excitations in Mn(dca)2(pyz) [dca = N(CN)2-, pyz = pyrazine]
J.L. Manson
H.N. Bordallo
J.W. Lynn
Q. Huang
R. Feyerherm
A. Loose
L. Chapon
D.N. Argyriou
Applied Physics A, 2002, 74 : s722 - s724
[7] Magnetic ordering and spin excitations in Mn(dca)2(pyz) [dca = N(CN)2-, pyz = pyrazine]
Manson, JL
Bordallo, HN
Lynn, JW
Huang, Q
Feyerherm, R
Loose, A
Chapon, L
Argyriou, DN
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2002, 74 (Suppl 1): : S722 - S724
[8] Synthesis, Structures, Spectroscopy, and Magnetic Properties of Pyrazine-Bridged Two-Dimensional Complexes {Ni(pyz)2(OCN)2}n and {Ni(pyz)2(SCN)2}n
Wang, Qing-Lun
Qi, Feng
Yang, Guang
Liao, Dai-Zheng
Yang, Guang-Ming
Ren, Hong-Xia
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (3-4): : 634 - 640
[9] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [FE(PYZ)2(NCS)2]N (PYZ = PYRAZINE), A 2D SHEET-LIKE POLYMER
REAL, JA
DEMUNNO, G
MUNOZ, MC
JULVE, M
INORGANIC CHEMISTRY, 1991, 30 (12) : 2701 - 2704
[10] Synthesis, structural isomerism, and magnetism of extended framework compounds of type [Cu(dca)2(pyz)]n, where dca = dicyanamide (N(CN)-2) and pyz = pyrazine
Chemistry Department, Monash University, Clayton, Vic. 3168, Australia
不详
不详
J. Solid State Chem., 2 (387-393):

← 1 2 3 4 5 →