Synthesis, characterization, crystal structure and theoretical calculations of an organotin(IV) complex with dithizone

被引：4
|
作者：
Delgado, Jorge A. [1 ]
Okio, Coco K. Y. A. [1 ]
Welter, Richard [2 ]
机构：
[1] Univ Nacl Colombia, Dept Quim, Bogota, Colombia
[2] Univ Strasbourg, Lab DECOMET, CNRS, UMR 7177, F-67000 Strasbourg, France
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 10期
关键词：
Dimethyl tin dichloride; Dithizone; Organotin complex; Crystal structure; LIGANDS; VALIDATION; CHEMISTRY;
D O I：
10.1016/j.inoche.2009.08.026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of dimethyl tin dichloride with 1,5-diphenylthiocarbazone affords the complex [Sn(CH3)(2)(Cl2H11N4S)Cl]. Its X-ray structure reveals a five-coordinated Sn atom in distorted trigonal bipyramidal geometry. The complex has been additionally characterized by IR and UV-Vis spectroscopy. Geometry optimization calculations support the experimental data. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：1074 / 1076
页数：3
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