Role of Dissolved Copper and Oxygen on Copper Sulfide Generation in Insulating Oil

被引：42

作者：

Kawarai, H. ^{[1
]}

Fujita, Y. ^{[1
]}

Tanimura, J. ^{[1
]}

Toyama, S. ^{[1
]}

Yamada, N. ^{[1
]}

Nagao, E. ^{[1
]}

Hosokawa, N. ^{[2
]}

Amimoto, T. ^{[2
]}

机构：

[1] Mitsubishi Electr Corp, Amagasaki, Hyogo 6618661, Japan

[2] Mitsubishi Electr Corp, Ako, Hyogo 6780256, Japan

来源：

IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION | 2009年 / 16卷 / 05期

关键词：

Copper; insulating oil; insulating paper; corrosive sulfur; oxygen; copper sulfide; dissolved copper;

D O I：

10.1109/TDEI.2009.5293957

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

We have developed a new heating test to investigate the influence of dissolved copper (DBDS-Cu complex) and oxygen on copper sulfide generation in alkyl benzene insulating oil with dibenzyl disulfide (DBDS) added. The weight of the deposited and dissolved copper was systematically studied in atmospheres of nitrogen and artificial air. The copper sulfide was deposited on the insulating paper using the heating test by separating the insulating paper from the copper strips in the insulating oil. It was found that dissolved copper (DBDS-Cu complex) has influence to the copper sulfide generation on the insulating paper. The weight of the copper deposited on the insulating paper was increased by the existence of oxygen. The acceleration effect on copper sulfide deposition on insulating paper was clarified for the first time by strictly controlling the experimental atmosphere. Moreover, the influence of the existence of oxygen was investigated individually on insulating oil and insulating paper. The oxidation of both alkyl benzene and insulating paper was found to accelerate copper sulfide generation.

引用

页码：1430 / 1435

页数：6

共 50 条

[1] Highly Sensitive Detection Method of Dibenzyl Disulfide and the Elucidation of the Mechanism of Copper Sulfide Generation in Insulating Oil
Toyama, S.
Tanimura, J.
Yamada, N.
Nagao, E.
Amimoto, T.
[J]. IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 2009, 16 (02) : 509 - 515
[2] Identification of Affecting Factors of Copper Sulfide Deposition on insulating Paper in Oil
Amimoto, T.
Nagao, E.
Tanimura, J.
Toyama, S.
Fujita, Y.
Kawarai, H.
Yamada, N.
[J]. IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 2009, 16 (01) : 265 - 272
[3] THE ROLE OF DISSOLVED-OXYGEN IN ELECTROLESS COPPER PLATING
MATSUOKA, M
HAYASHI, T
[J]. METAL FINISHING, 1985, 83 (06) : 85 - 90
[4] Saturated Dissolved Oxygen Concentration in in situ Fragmentation Bioleaching of Copper Sulfide Ores
Huang, Ming-Qing
Zhang, Ming
Zhan, Shu-Lin
Chen, Lin
Xue, Zhen-Lin
[J]. FRONTIERS IN MICROBIOLOGY, 2022, 13
[5] Thermodynamic potentials of oxygen dissolved in copper
Matousek, J. W.
[J]. JOM, 2010, 62 (03) : 75 - 77
[6] Thermodynamic potentials of oxygen dissolved in copper
J. W. Matousek
[J]. JOM, 2010, 62 : 75 - 77
[7] Copper dissolution and metal passivators in insulating oil
Wiklund, Per
Levin, Martina
Pahlavanpour, Bruce
[J]. IEEE ELECTRICAL INSULATION MAGAZINE, 2007, 23 (04) : 6 - 14
[8] Development of Quantitative Evaluation of Copper Sulfide Deposition on Insulating Paper
Kawarai, H.
Fujita, Y.
Tanimura, J.
Toyama, S.
Yamada, N.
Nagao, E.
Amimoto, T.
[J]. 2008 IEEE CONFERENCE ON ELECTRICAL INSULATION AND DIELECTRIC PHENOMENA, 2008, : 187 - +
[9] INHIBITION OF DIFFUSION CREEP IN COPPER BY DISSOLVED OXYGEN
HONDROS, ED
LAKE, CR
[J]. JOURNAL OF MATERIALS SCIENCE, 1970, 5 (05) : 374 - &
[10] Effects of Electric Fields on Copper Sulfide Deposition and the Properties of Insulating Oils in Oil-Immersed Transformers
Yang, Li-jun
Gao, Si-hang
Deng, Bang-fei
Tang, Jie
Huang, Jia-jia
[J]. IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 2017, 24 (05) : 2847 - 2853

← 1 2 3 4 5 →