Electrospun Cobalt-Doped MoS2 Nanofibers for Electrocatalytic Hydrogen Evolution

被引:9
|
作者
Rheem, Youngwoo [1 ]
Park, Sun Hwa [2 ]
Han, Yosep [1 ]
Lee, Kyu-Hwan [3 ]
Choi, Sung-Mook [3 ]
Myung, Nosang V. [1 ]
机构
[1] Univ Calif Riverside, Dept Chem & Environm Engn, Riverside, CA 92521 USA
[2] Korea Res Inst Stand & Sci, Ctr Convergence Property Measurement, Deajeon 34113, South Korea
[3] Korea Inst Mat Sci, Surface Technol Div, Chang Won 51508, South Korea
关键词
ULTRATHIN NANOSHEETS; EDGE SITES; CARBON; METAL;
D O I
10.1149/2.1041912jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Cobalt (Co)-incorporated MoS2 nanofibers were fabricated via a facile electrospinning method followed by sulfurization process. Co atoms in the molybdenum oxide nanofibers altered the morphology and crystal structure according to sulfurization time. The well-anchored Co-incorporated MoS2 sheets on the nanofiber surface acted as active edge sites for the hydrogen evolution reaction (HER), which exhibited high activity with an onset potential of approximately -170 mV vs NHE with a Tafel slope of 60 mV/dec. The overpotential was -330 mV vs NHE at 10 mA/cm(2). (C) 2019 The Electrochemical Society.
引用
收藏
页码:F996 / F999
页数:4
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