Intracavity absorption spectroscopy of HCl isotopes, H2O, CH4, C2H4, and C2H6 in the 3.1-3.4 μm spectral range using a Cr:CdSe laser

被引：3

作者：

Fjodorow, Peter ^{[1
]}

Frolov, Mikhail P. ^{[2
]}

Korostelin, Yuri V. ^{[2
]}

Kozlovsky, Vladimir I. ^{[2
]}

Schulz, Christof ^{[1
]}

Leonov, Stanislav O. ^{[2
]}

Skasyrsky, Yan K. ^{[2
]}

Yuryshev, Nikolai N. ^{[2
]}

机构：

[1] Univ Duisburg Essen, Inst Combust & Gas Dynam React Fluids, Carl Benz Str 199, D-47057 Duisburg, Germany

[2] Russian Acad Sci, P N Lebedev Phys Inst, Leninskiy Prosp 53, Moscow 119991, Russia

来源：

OPTICS EXPRESS | 2022年 / 30卷 / 22期

关键词：

COMB SPECTROSCOPY; DYNAMICS; VAPOR;

D O I：

10.1364/OE.471851

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We demonstrate the first application of a Cr:CdSe laser for highly-sensitive multi-component intracavity absorption spectroscopy around lambda = 3.1-3.4 mu m. A detection scheme based on an integrated recording of multiple (similar to 70) individual Cr:CdSe laser pulses after a single pump-pulse excitation is reported. The sensitivity of our system corresponds to an effective absorption path length of L-eff 850 m. Exemplary measurements of atmospheric H2O and CH4, and additionally introduced gas-phase HCl, C2H4, or C2H6 are presented. The achieved noise-equivalent detection limits are in the ppb range. Possibilities for further sensitivity enhancement by up to a factor of 10(4) are discussed. (c) 2022 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement

引用

页码：40347 / 40356

页数：10

共 50 条

[1] Computational screening of MOFs for C2H6/C2H4 and C2H6/CH4 separations
Altintas, Cigdem
Keskin, Seda
CHEMICAL ENGINEERING SCIENCE, 2016, 139 : 49 - 60
[2] STUDY OF INTRACAVITY ABSORPTION AND LASER BEHAVIOR FOR C2H4, C2H6, CH3F, CH3CL, AND CH4/N2 BY PHOTOACOUSTIC RESONANCE SPECTROSCOPY
ROPER, J
NEUBRAND, A
HESS, P
JOURNAL OF APPLIED PHYSICS, 1988, 64 (06) : 2838 - 2846
[3] Elastic differential electron scattering from CH4, C2H4 and C2H6
Mapstone, B.
Newell, W.R.
Journal of Physics B (Atomic and Molecular Physics), 1992, 25 (02):
[4] MULTICONFIGURATION SELF-CONSISTENT WAVEFUNCTIONS FOR CH4, C2H4 AND C2H6
LEVY, B
CHEMICAL PHYSICS LETTERS, 1973, 18 (01) : 59 - 62
[5] The effect of nitric oxide on premixed flames of CH4, C2H6, C2H4, and C2H2
Williams, BA
Pasternack, L
COMBUSTION AND FLAME, 1997, 111 (1-2) : 87 - 110
[6] AN XPS INVESTIGATION OF THE INTERACTION OF CH4, C2H2, C2H4 AND C2H6 WITH A BARIUM SURFACE
VERHOEVEN, JAT
VANDOVEREN, H
SURFACE SCIENCE, 1982, 123 (2-3) : 369 - 383
[7] 简化三维比值（C2H2/C2H4,CH4/H2,C2H4/C2H6）图的应用
徐秉天
华北电力技术, 1990, (Z1) : 89 - 91
[8] KINETICS OF DEPLETION OF ELECTRONICALLY EXCITED TI ATOM BY CH4, C2H2, C2H4 AND C2H6
HONMA, K
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1995, 42 (02) : 371 - 379
[9] EFFECT OF ADDED AMMONIA ON REACTIONS OF ACTIVE NITROGEN WITH CH4, C2H6, AND C2H4
WRIGHT, AN
WINKLER, CA
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1962, 40 (07): : 1291 - &
[10] LOW-ENERGY-ELECTRON SCATTERING FROM CH4, C2H4 AND C2H6
LUNT, SL
RANDELL, J
ZIESEL, JP
MROTZEK, G
FIELD, D
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1994, 27 (07) : 1407 - 1422

← 1 2 3 4 5 →