Studies on the reaction of 1,2,3-trisubstituted electron-deficient cyclopropane derivatives with methanol

被引：0

作者：

Cao, WG ^{[1
]}

Ding, WY

Tong, WQ

Liu, X

Qiu, MY

机构：

[1] Shanghai Univ, Dept Chem, Shanghai 201800, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2000年 / 21卷 / 05期

关键词：

1,2,3-trisubstituted cyclopropane; methanolysis; methyl butyrate;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this paper, the reaction of 1,2,3-trisubstituted electron-deficient cyclopropane derivatives cis-1-benzoyl-2-p-substituted phenyl-6, 6-dimethyl-5, 7-dioxo-spiro-[2, 5]-4,8-octadiones with methanol was studied. The structures of the reaction products were confirmed as methyl beta-benzoyl-gamma-methoxy-gamma-p-substituted phenylbutyrates by means of IR, MS, microanalysis, H-1, C-13 NMR spectroscopies and APT techniques. The reaction mechanism for the formation of the product was also proposed.

引用

页码：740 / 742

页数：3

共 8 条

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