Peanut shell as a green biomolecule support for anchoring Cu2O: a biocatalyst for green synthesis of 1,2,3-triazoles under ultrasonic irradiation

被引:23
|
作者
Dolatkhah, Zahra [1 ]
Mohammadkhani, Abolfazl [2 ]
Javanshir, Shahrzad [1 ]
Bazgir, Ayoob [2 ]
机构
[1] Iran Univ Sci & Technol, Dept Chem, Heterocycl Chem Res Lab, Tehran 1684613114, Iran
[2] Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran
关键词
Bio-based support; Click reaction; Heterogeneous catalyst; Peanut shell; Triazoles; Ultrasonic irradiation; ONE-POT SYNTHESIS; REUSABLE CATALYST; 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES; HETEROGENEOUS CATALYST; IODIDE NANOPARTICLES; CLICK SYNTHESIS; IONIC LIQUID; COPPER; TRIAZOLE; NANOCOMPOSITE;
D O I
10.1186/s13065-019-0612-9
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cu2O supported on peanut shell (Cu2O@PS) was prepared by the reaction of copper acetate and peanut shell powder as a naturally available biopolymer support. The prepared catalyst was used as an efficient and reusable heterogeneous catalyst in the click reaction of benzyl halide or phenacyl bromides, acetylenes and sodium azide for the synthesis of potentially biologically active 1,2,3-triazoles under ultrasonic irradiation in EtOH-H2O as green solvent.
引用
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页数:10
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