Sulfated zirconia as a solid acid catalyst for the dehydration of fructose to 5-hydroxymethylfurfural

被引：176

作者：

Qi, Xinhua ^{[1
,2
]}

Watanabe, Masaru ^{[1
]}

Aida, Taku M. ^{[1
]}

Smith, Richard L., Jr. ^{[1
]}

机构：

[1] Tohoku Univ, Res Ctr Supercrit Fluid Technol, Aoba Ku, Sendai, Miyagi 9808579, Japan

[2] Nankai Univ, Coll Environm Sci & Engn, Minist Educ, Key Lab Pollut Proc & Environm Criteria, Tianjin 300071, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 13期

基金：

日本学术振兴会; 中国国家自然科学基金;

关键词：

Sulfated zirconia; Fructose; 5-Hydroxymethylfurfural; Solid catalyst; ION-EXCHANGE-RESIN; CONVERSION; SO42-/ZRO2; PHOSPHATE; WATER;

D O I：

10.1016/j.catcom.2009.05.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sulfated zirconia was prepared by impregnation with H2SO4, and was characterized using BET Surface area, XRD, TG-DTA and FNR techniques. The sulfated zirconia was evaluated as a catalyst for the dehydration of fructose to 5-hydroxymethylfurfural (5-HMF) by microwave heating. With sulfated zirconia catalyst, high fructose conversion of 93.6% with 5-HMF yield of 72.8% could be attained at 180 degrees C for 20 min reaction time in acetone-dimethylsulfoxide (DMSO) mixtures. Sulfated zirconia is an effective catalyst for producing 5-HMF from fructose in non-aqueous solvent but shows low catalytic activity in water solvent. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1771 / 1775

页数：5

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