A study of the reaction of adenine with ethylene oxide or with ethylene carbonate

被引：8

作者：

Lubczak, R ^{[1
]}

Duliban, J ^{[1
]}

机构：

[1] Rzeszow Univ Technol, Fac Chem, PL-35959 Rzeszow, Poland

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2002年 / 52卷 / 03期

关键词：

adenine; ethylene oxide; ethylene carbonate; polyetherols; purine ring;

D O I：

10.1016/S1381-5148(02)00085-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A study on the reaction of adenine with ethylene oxide or with ethylene carbonate at different molar ratios of reagents is described. For both pairs of reagents, nominally, the same products were obtained. At first, N(9)-2-hydroxyethyl derivative of adenine was obtained, and then, polyetherols containing purine rings. The main difference between the reactions carried out using the oxide and carbonate was the resulting substitution degree of amine group. The course of both types of reactions was followed using H-1 NMR spectroscopy to determine the contents of amine, hydroxyl, and methylene groups in the products of reactions. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：127 / 134

页数：8

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