Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones

被引：21

作者：

Matsukawa, Satoru ^{[1
]}

Sekine, Izumi ^{[1
]}

Iitsuka, Ayumi ^{[1
]}

机构：

[1] Ibaraki Univ, Fac Educ, Dept Sci Educ, Ibaraki 3108512, Japan

来源：

MOLECULES | 2009年 / 14卷 / 09期

关键词：

organocatalysis; cyanosilylaton; cyanohydrin carbonate; phosphines; cyanation; BAYLIS-HILLMAN REACTION; TRIMETHYLSILYL CYANIDE; ASYMMETRIC CYANATION; CYANOHYDRIN; CONVENIENT; ESTERS;

D O I：

10.3390/molecules14093353

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields in the presence of 1-5 mol% of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP). Cyanohydrin carbonates were also readily prepared using 5-10 mol% of TTMPP as an organocatalyst.

引用

页码：3353 / 3359

页数：7

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